The DBC has an olive tone to it. Of the 2, I agree, the DCC looks the most accurate.
Usually the 2 types should look identical, with the clear coat giving the DBC a better gloss...and much more durable shine. I would imagine they have trouble mixing exactly with such small samples. I used to use paint scales to balance engine parts as they are the most precise scales I have ever found. The smaller the paint sample they mix, the more difference a small mix error makes.
The DCC is most popular in trunks and engine bays, where it is difficult to uniformly spray the clear back over the base.
For planning, my TR3, painting the entire tub and all the back sides of the wings, bonnet, apron, etc., it took 1-1/2 gallon of the DBC. Every time I pay $2k just for the paint on a restoration, I think of my Old Man, who used to put $100 MAACO paint jobs on all his cars. Of course, his paint looked good for a month. Modern Urethanes last decades.