Original configuration was positive ground.
However, none of the original components care very much, the car will actually work (more or less) if you just swap the battery leads. (Sometimes they get swapped by accident.) Normally, it's best to also swap the leads at the coil (plugs fire easier with a negative spark) and ammeter (it will read backwards otherwise). The original generator can be "polarized" to operate either way. The battery posts are slightly different sizes, but usually the clamps will accommodate either post.
If someone has added an outlet for charging a cell phone, or an electric radiator fan, it will need attention too.
Of course, if you have an alternator, or anything else with electronics in it (LED bulbs, stereo, etc), you'll probably want to stick with negative ground. I knew I would probably want to convert to an alternator in the future, so I put my TR3 together as negative ground. (Positive ground alternators do exist, but are very hard to find and may not fit very well.)
PS, welcome to the asylum!