Hi,
I don't know if it applies to them so wouldn't generalize these comments to the the later 6-cyl. or smaller 4-cyl. Triumph motors...
But the 4-cylinder TR3/4 head is a lot more resistant to valve seat recession problems than some (most?) other cars of its era. It has to do with the alloy that Triumph originally used when casting the head, which has proven pretty durable even with fuel changes. This is from a metallurgist and a long-time TR racer/engine builder, that the cars will survive pretty darned well with unleaded gas *unless they are driven quite hard*. High rpms and heavy use of the engine (racing conditions) *are* more likely to cause valve seat problems in this particular engine.
Another key unleaded issue, the valve guides, are more likely to see a problem. The original guides partly relied upon lead in the fuel for some lubrication. This is particular true on the hot/exhaust side. Worn orignal guides that allow a bit more oil in are probably helped to survive thanks to that little bit of additional oil (although that means more oil ends up getting burning in the combustion chamber).
Replacement guides are now generally unleaded fuel compatible (phosphor bronze? which has more self-lubricating properties), but check the archive about warnings on properly fitting these (going by original factory specs can cause valve stem seizure).
Finally, the original valves themselves hold up pretty well, but it's recommended to convert to stainless steel valves, especially on the exahust side, to handle the higher temps typical of unleaded fuel.
No fuel additive sold over the counter in the U.S. has any lead in it. It's illegal to import or sell. Other less-effective-than-lead, but possibly helpful additives are substituted. There have been some extensive studies of the different products, their additives and their effectiveness, you might google for this info on the Internet.
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