Kevin,
In addition to raising the effective octane, the TEL also formed a coating on surfaces in the combustion chamber. Among other things, this coating helped prevent the exhaust valve seats from eroding, due to micro-welding with the (very hot) valve heads after every exhaust stroke. When lead started being phased out, the valves and valve seats were upgraded (hardened) so they no longer needed the TEL to prevent erosion.
However, in many cases, the coating left from previous running on leaded fuel will last a long, long time; possibly for the life of the engine. And adjusting the valves is routine maintenance; relatively easy to learn to do, and requires a minimum of tools.
So, my (and many experts who know better than I do) advice is to learn to adjust the valves yourself, and keep an eye on them. If you find that the exhaust valves (valve seat recession only affects exhaust valves) are routinely too tight after only a few thousand miles of driving; then you will know you have a problem and can start saving for a valve job. It does absolutely no harm to "wait and see", since the parts that are being damaged are exactly the same parts that have to be replaced to do the upgrade.
The upgrade itself is not a job for a novice, IMO. Depending on how much you want to learn, you can do the majority of the 'grunt' work yourself by removing the cylinder head from the engine. But after that, I would suggest taking the head to an automotive machine shop to have the actual work done. They will use an assortment of expensive special tools to mill out the old exhaust seats (which are part of the cylinder head casting) and press new hardened seats into place; then machine the seats to accurately match the (new) valve heads. They will also replace valve guides as needed (more special tools); and check whether the valve springs need to be replaced (good chance they do). They should also check the head for flatness, and machine it flat if necessary.
You can call around for prices, but I would guess that a complete valve job on a 6-cyl head would run something like $400-$600 with parts. This is very standard work for auto machine shops; so you don't necessarily need to find one that specializes in British cars.
On the carb rebuilding; there are many different levels of "rebuild". Most commonly, they just need to be cleaned thoroughly and have a few parts replaced (seals, diaphragm, gaskets, etc.), then adjustments made. This is something a novice can easily learn to do, using common hand tools and a few relatively inexpensive special tools. Poke around on this forum a bit; I think someone recently posted a link to a good series of articles on the web showing exactly how to do the carb rebuild. If not, send me a PM with your email address; and I'll forward the articles to you in PDF form.