I make up the batch based on what I have to paint. For the entire tub, I'd likely mix the full 36 oz. cups. I have even gotten very lazy and actually mix the paint IN the cup, instead of in jars like I used to do. If I need more, I pop the top and mix more in the same cup I am using. Just remember to give it 15 minutes for the catalizer to start before you spray.
For spraying primer, use the largest tip you have. The smaller tips will tend to clog with the thickness of the primers. For finish, switch to a small tip for a finer spray pattern.
On areas that will require a lot of sanding and re-priming, I always spray a light primer coat of one color, followed immediately with a thicker coat of a different color primer. That gives you a sanding guide, so when the first coat starts to show through, you know to stop sanding before you hit metal. You cannot have bare metal under your color coat. It will not bond right.
I screwed up a batch last month while showing my son how to paint his fender. All 2-part paints have a pot life...so once mixed you have to spray within the pot life. I got talking to him, giving tips and such, and failed to realize we had exceeded the primer's pot life. I should have known when it wasn't laying right as we sprayed. Sure enough...it did not bond right, and the entire layer had to come back off and get re-sprayed from scratch.
Pot life is shortened in hot weather, or if you went a bit over on the mix ratio. Something to be aware of while you spray.
One of the beautiful things about the 2 part primers is they harden very fast. With most primers you can sand after just 30 minutes. Of course, read the spec sheet to be sure...