Boy am I'm late to the conversation. I thought this guy should not be doing photography videos. He misspoke so many times it really affected his credibility in my opinion.
Well, of course I really am a neophyte. Most of what he said made sense to me, but I'm as far from a pro as you can get. I do agree the commnt about setting the Fuji Dynamic Range to 200 or 400 confused me and I'm sure he didn't mean to imply that the Fuji cameras have a DR that huge.
Setting that confusing bit aside, I do know that if I overexpose the highlights in my 5D MarkIV I can not, no matter what I do, recover the detail in those highlights after the fact. Once they are lost in camera, that's it, they are gone. Conversely, if I expose FOR those highlights, so that I have the desired amount of detail there, then the blacks can get crushed a bit but I can usually bring up the shadows in Lightroom and recover the detail in the shadows. That's why, if I can expose for the sky or bright background without killing my shadows, that's usually what I do.
As for how to meter for the highlights, I'm "guessing" he assumed most people already understand how most digital cameras do metering. He stated up front that, once you go down the rabbit hole of exposure, it could become a much longer video and he wanted to just ht some key points.
I think I looked at this as just a basic discussion of exposing to the left vs exposing to the right and to that end I thought he was mostly on point.
First off, Sitting at your computer at home is way too late to expose anything.
As long as I haven't blown out my highlights I can almost always recover the shadows and get a nice, balanced overall exposure after the fact. Lightroom has cool tools. that I really love, such as "Sky Masking", which masks just the sky and allows you to adjust pretty much anything to your desire (+/- exposure, highlights, shadows tone, contrast etc, and those adjustments only affect the sky. You can also, "invert" the mask so that your adjustments affect everythign but the sky (i.e., the foreground and subject). That's just the tip of the iceberg. If I'm shooting a sunset, for example, I can't get perfect exposure in the foreground and the sky unless I'm shooting in-camera HDR (which I do sometimes). Otherwise, as I said, I usually try to get the sky right with no blown out highlights so it looks good, then I recover the shadows in post. I usually look at my histogram and see what the blacks and highlights are doing (is anything blown out or any blacks completely crushed).
For your bonus round, I too thought the subject looked a bit over exposed, but then he was just making a point about exposing for blacks vs whites I think.