Hi Mike,
I agree with Andy in most respects. Many of the additives are not worth the extra expense. Some seem to do more harm than good in the long run, might only offer a very temporary solution, at best.
I will make an exception for Bar's Radiator Stop Leak.
I have personally used it with good success in several cars that were otherwise impossible to keep the coolant out of the sump. (Such as a friend's Pontiac with a 2.1L engine that's notorious for this and overheating problems in general... Bars has been in there and done the job for 4-5 years now... This was after extensive work on a warped and cracked cyl. head by a dealer and my own efforts replacing the water pump, installing a new thermostat, new hoses and clamps, etc., etc.)
BTW, Bars has been OEM specified by GM for some years for use in all-aluminum or aluminum head engines in Cadillac and others. It's right in the factory service manual.
Your previous questions about white "smoke" and recently noticing a puff of it when the car was first started in the morning *really* lead me to believe you have a slow, seeping leak in the head gasket.
You say there's little or no indication the coolant is getting into the sump and mixing with the oil, which likely means it's only getting into one or more cylinders and the head gasket is sealing pretty well otherwise.
I'd also try to find out why the coolant header or overflow tank is dry. It shouldn't be. It should be fuller when the engine is hot (and the coolant expands out of the system into the tank) and drop to about one third or half-full when the engine is cold (and coolant is drawn back into the system, rather than air).
Even if the radiator itself appears full when cold, if that header/overflow tank is empty, some air is probably getting into the cooling system. When that happens, steam is created, leading to more leaks and hot spots, and can do damage to the engine pretty quickly. In fact, steam or hot spots might be the cause of a small head gasket leak, or could be the result of one. Plus, a leaky head gasket might seal when warmed up, only to leak again when the engine is cooling down. Or, it could be that when warmed up and running hot exhaust gases are pushing past the head gasket into the cooling system, compounding the problem.
If the overflow/header tank level keeps dropping, especially so dramatically that it's dry in a short time, there is a problem that needs addressing. If you don't see any coolant on the ground, it's gotta be going into the engine. If not in the sump, it has to be going into a cylinder and then out the tail pipe. If you half-fill the overflow/header tank with a pint or two of coolant and then find it dry after a day or two or three, *a lot* of coolant is finding it's way through the engine.
But, before resorting to additives, try torquing the cylinder head nuts to see if any are loose and if that might pull the head down better to stop a leak. (The head also might be warped and impossible to pull down adequately, as a result of localized overheating). I don't have a manual in front of me to check the torque specs for Spitfire cylinder head nuts and the correct tightening sequence. Hopefully you have a manual for reference and a good torque wrench to use, or can borrow one.
If re-torquing the head doesn't help, Bars might help temporarily and might be a good diagnostic tool, although I'd not necessarily consider it a long-term solution. If it's leaking the head gasket ultimately should be replaced, as Andy said. But, if you add some Bars to the radiator, the white "smoke" stops and the overflow/header tank keeps some level of coolant in it, you have certainly identified the problem as a head gasket leaking a little coolant into one or more cylinders.
Adding Bars might also not help, in which case the head gasket is just leaking too much and has to be replaced before the car is driven much.