I actually don't use them yet, still using a brass setup I got from BFE many years ago. I've got a set of Delrin on the shelf (from Joe A), but probably won't ever actually use them. Even after some 20 years of service, there was no wear apparent in the brass.
If you are worried about the pin taper not matching the taper in the center link, I suggest a trial assembly of just the pin into the center link. It should fit snugly, no wiggle at all, with only finger pressure. If you want, you can do a further check by painting the pin with machinists blue, and giving it a slight twist in place. The blue will rub off only where the two tapers are in contact.
If the problem is just that there isn't enough if the pin protruding, just check that the joint will still turn after torqueing the nut. The Delrin is relatively soft and will crush under force. So the taper will seat, the only question is whether the Delrin crushed too much. I normally use a regular nut at first, to get the taper locked, so it will hold the pin while installing the Nyloc.
FWIW, I actually trimmed one of the brass bushings to fit, and added shims to the other. The bushings were the same, the variation was in how deep the tapers were in the center link.
Locking tapers are a time honored solution, they work very well. Sometimes a little too well, as anyone who has struggled with a rear hub can attest. They are still in common use today!