Hi Ron,
I've heard this elsewhere, but the cans specifically state it is not flammable. Also, on
https://www.freeze12.com it states "FREEZE 12™ is non-flammable and contains no CFC'S." I believe it's 80% R134a. On the rennlist forum there was a heated debate about the merits or otherwise of Freeze-12. Some folks despise it, and others say it works just fine. I'm going to give it a try, because I'm a born experimentalist, and there doesn't seem much to lose (my A/C is blowing warm: I had it refilled with R12 last year for around $200, and I don't fancy that again).
But I do thank you for your warning, which makes me quite (even more) cautious.
For the valve problem, I just figured it out. On closer examination of the valves and couplers, it's apparent that the converter coupling's valve pin is pushed in by the coupler hose fitting, and it then pushes in the pin on the R12 adapter valve, so opening the passage. Ther coupler hose fitting has a small protrusion in its centre that pushes on the pin as the coupler is screwed and tightened on the adapter.
My problem was that this protrusion was not adjusted correctly: it wasn't pressing the pin in far enough to engage and push the R12 pin in. After adjusting it somewhat, I can hear gas escaping from the R12 valve when I screw in the coupling hose.
So tomorrow I am going to try a fill.
I like the idea of having two valves in series: makes a leak much less likely!