Hi,
Yes, there are a number of places to wipe on a little grease. I suggest anywhere the frame of the shoe rubs against the backing plate, under the slave cylinders and in the adjusters, plus the slots where the shoes fit into the slave cylinders. Basically, anywhere there is rubbing and metal to metal contact.
Just a little is needed and you are right to keep it off the shoe lining and inside of the drums. .
As to the fitting problem, are you sure the parking brake is fully off? (been there, done that)
Put pressure on the shoes with your (clean) hands to be sure they are fully retracted. Also it sometimes helps to tap the shoes with a rubber mallet or the heal of your hand, top and bottom, to get them to fully seat in both the adjuster and the slave cyl. That's really all "centralizing" is, working to get the shoes back in place properly, pretty much by eye (although there might have been a special Churchill tool for it!) Keep trying, they can be stubborn at first.
I have heard of folks having trouble with too thick lining on shoes. But, I think the last time it was the special kevlar-type shoes that couldn't be made to fit. You might compare with your old shoes, to see if the lining might be too thick.
Are your drums new or, if used, have they been turned to remove any ridge that might have been formed?
Alan Myers
San Jose, Calif.
'62 TR4 CT17602L