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Other things to check :
Head surface is flat and not distorted.
That the stud threads are not distorted and are long enough that the nut clamps only onto the manifold (through the bridge pieces).
No burrs or other defects on either sealing surface.
Manifold isn't hitting anything else. (Not sure about a TR6, but TR3 manifolds sometimes foul on the edge of the cylinder block.)
Nuts are in good condition and spin easily all the way down the threads; spring washers still have their spring. I usually find the spring (lock) washers need replaced almost every time I have the manifolds off.
I've also found it helpful to check the nuts for tightness occasionally (I make it part of my major tune-up procedure).
Not sure if this would apply to a TR6, but on a TR3 there is no flat washer or bridge piece on the outermost studs. Adding a thick flat washer between the lockwasher and the manifold made a difference for me.
You shouldn't need any sealant on those gaskets, IMO. If everything is right, they'll seal fine. And if something is wrong, it should be fixed.