Is there any value to adding a PCV valve from the valve cover to the intake manifold?
Well, maybe, but it would be a lot more complicated than that. If you design a proper PCV system, the main advantage would be to cut back on the pollution that comes out of the road draft, both unburned hydrocarbons and the occasional drop of oil.
But just hanging a valve from the rocker cover to the intake manifold would suck dirt and grit up off the road back into the crankcase. Probably not such a good idea.
And if you just blank off the draft tube port (as Triumph did), that allows pressure to build up in the crankcase during full throttle operation (when there is no intake vacuum to suck fumes through the valve) which will blow oil out in other places (like the rear main seal). It also allows the blowby gases to condense and contaminate the oil, forming varnish and sludge. Also not a great idea, IMO.
To really do it "right", you need to provide a filtered fresh air intake to the crankcase, preferably arranged so that when flow through the valve is not sufficient, the gases flow backwards through the crankcase vent and get sucked into the carb intakes. I'd really like to try that some day, but haven't found the right round tuit as yet.
I'm thinking maybe cut off the top of the road draft tube and put a PCV valve there, linked to the intake manifold. Then an air box with a single large paper element air filter on the carbs, with a line (and perhaps some sort of oil trap) to the rocker cover. You could also add an air duct to bring fresh cold air around the side of the radiator, instead of sucking hot air through the radiator.