I suspect that your only source for an original connector will be to steal one off an existing unit or wiring harness. However, there is no real need to use the correct one, unless you're really picky about originality.
I don't have a lot of experience with these instruments--there are several kinds. Some are as simple as a little loop of wire on the back of the can, and others have the loop embedded in a piece of plastic inside the can with connector pins molded into the plastic and protruding from the back. I suspect you have the latter, it being a 66 car. If so, it probably have a combination of bullet connectors and 1/4" spade lug--so you can just use a separate bullet and spade connector to attach to it. If you can't find a connector that fits, consider soldering a short piece of wire to the existing connectors and using whatever other connector you can find. Be careful if the pins are mounted in a plastic piece-it's easy to melt this with a soldering iron. Polarity is important--so, if it doesn't work, first thing to try is reversing the connections.
The way these work is pretty simple: the loop is in series with the ignition primary, so every time a plug fires, there is a pulse of current in the loop. This creates a pulsed magnetic field which is sensed by the tach, and triggers a pulse in the electronics of the tach. The faster the pulses, the higher the speed. The important thing to remember is this: the loop is in series with the ignition system, so if it open-circuits, you lose ignition and the car just won't go. So, be SURE you make good connections!
As for the Pertronic ignition--can't say for sure, since I'm unfamiliar with this unit. I have a Crane, and the instructions for the Crane address this specifically. I suspect it should work--the electronic ignition just generates a pulse in the coil, same as the non-electronic one. It's just that the pulse is a somewhat different. The tach circuit has to be pretty versatile in dealing with a wide variation of pulse shapes, which is what happens in an ordinary ignition, so I'd expect that there is a better than 50-50 chance it will work.