Won't hurt the generator at all, Andy, assuming you remember to polarize the field and not the armature
When you first start the engine, there is almost no field current to the generator. The voltage regulator contacts have the field connected to the armature, but the cutout is open, isolating both from the battery (except for a very small current through the red warning light). However, there is some residual magnetism left in the outer housing of the generator, which is enough to generate just a little bit of voltage. That little bit gets fed back to the field coils, making a stronger magnetic field, which produces more voltage, etc. and it quickly comes up to where the cutout contacts close.
When you "polarize" the generator, you are setting up that residual magnetic field with the proper polarity for your electrical system. When you polarize the other way, the magnetic field gets flipped around as well. You can flip it as often as you like, won't hurt anything at all.
However, I would suggest remembering to polarize <span style="text-decoration: underline">before</span> starting the engine. Otherwise the cutout contacts may close with 24 volts across them, which isn't exactly good for them
