Keoke, if the car has already been converted to negative ground, then the power wire (i.e. the green one that comes from the fuse box via the fuel gauge) will show +12 volts when the positive lead of a voltmeter is connected to it and the ignition switch is on, and the white wire at the coil will show the same. But that doesn't indicate whether the tach itself has been converted. The only external change to the tach for negative ground is the direction of the loop in the white wire on the back of the tach. This can be a bit confusing, but if the tach has been modified for negative ground the loop should look like the photos below that I made after the conversion of my car. The one on the right shows the tach from under the dash.
The only other way to determine whether the tach has been converted is to open the case and look at the tach guts. There are only two connections that need to be reversed to convert from positive to negative ground, as shown in the other photo.
However, it doesn't cause any damage to the tach to connect it either way. It just won't work if the modifications haven't been made to the appropriate polarity or the loop is in the wrong direction.