Actually, Moonie is on the right track. Headers tend to actually lean the mixture slightly. A lean mixture tends to burn hotter; more fuel tends to cool the mixture. This was actually one of the earliest attempts used by manufacturers to acheive the federal emission control standards that went into effect in 1968. Mixtures were leaned, thus making higher combustion temperatures, which in turn resulted in more complete combustion, and less hydrocarbon (HC) emissions. Some manufacturers also installed hotter thermostats for this reason also, and different heat range plugs, different timing, etc.
Too lean a mixture is also a good recipie to burn exhaust valves.
Higher combustion temperatures, though, resulted in higher Nitrogen Oxide (NOx) emissions, the result of which was the Exhaust Gas recirculation (EGR) valve on cars beginning in the early 1970s.
Paul's idea of insulating the fuel line has merit. You probably have vapor lock from that heat, as a result of high underhood temperatures. This is the reason that a lot of the old hot rodders louvered their hoods (or diched the hood altogether).
This is why serious drag racers sometimes install cool cans.
Colin
Colin