Since I started using lead-free in 1990, I have never had run-on in my 1958 TR3A during 99,000 miles of driving. The engine temperature was often hot wen I shut off the engine and it never did it.
I removed the head in 2000 after 43,000 miles on the new engine (at 80,350 miles) to have exhaust valve seats installed for lead-free gas and the head was clean. There was nothing there to "de-coke". Again last spring when I rebuilt the engine, there were no deposits to create "hot spots" with the lead-free gas. This was 51,000 miles after the earlier time I removed the head.
If the head on your TR still has leaded gas residues in the combustion chamber, then these hot-spots might be the cause.