Keeping four SUs working, adjusted right, and synced--now there's a scary thought!
The use of two carbs is just to get enough air/fuel mixture into the cylinders with minimum flow resistance, which means the straightest line. I suspect there may have been a nod in the direction of satisfying people's expectations, too, when these engines were designed. Car enthusiasts felt that two carbs were better than one, end of story. At least in theory, it may be possible to do as well with one big carb instead of two smaller ones (e.g., the Leyland 1500 on Spitfires and late Spridgets) and probably would be less expensive and more reliable. But two carbs is way cooler.
Oh, yes, the front carbs mostly feed cylinders 1 & 2, and the rear 3 & 4, but the two pipes are linked by that cross piece in the manifold, so it's not quite that simple.