I recommend you run it down to your friendly local gas station, give the wrench there a couple bucks to use his impact on the nut. Another alternative is if you have a "strap" wrench. Which will wrap around the pulley, emulating a belt, that can be held down by someone while you are trying to torque on the nut. Usually though, with mileage and time comes surface corrosion, which fills in the thread openings between the nut and the shaft of the alternator.
That is why I recommend an impact, as the sudden jolt breaks the surface tension. When you reassemble a little(key word is little) antiseize applied will help anyone in the future to disassemble the pulley. The fan blade can usually be straightened to near original shape. If you haven't removed any metal there should be no affect on the rotation. I have seen a few come with weights welded(soldered) on, but that's a rarity anymore.