I just finished building a 12.5:1 compression Camaro in 1979. They removed the lead and dropped the octane that same year. I had to make trips to the local airport to get avgas...which is actually 100 octane low lead...(and has been since WWII). It took more than a cup or two, though. Closer to a 1 part avgas to 2 parts no-lead. The lead in the avgas raises the octane of the no- lead several points. "Low-lead" in avgas is still higher lead than we used to have at the pump, by the way.
There are legality issues. Both you and the seller can be fined if they catch you using the avgas on the road. I had them pump it into cans that I transferred to the car. The good news, it is not dyed like the No. 2 farm diesel is, so once it's in the tank they can't prove what it is. One extra bonus...no alcohol is in avgas!
After 2 years of this ritual, and a car I could never take on road trips, I rebuilt the motor to take pump gas. Till you brought up avgas I forgot all about that engine! By the way, I was much happier loosing a little torque but having a car I was not always afraid would detinate to death.
John
PS...There is fuel out there up to 120+ octane, but it is specialty racing fuel...not standard avgas.