Right, the whole carb thing was to meet US emission requirements. The story I read said that Lucas had assured Triumph/Leyland that their PI system could meet US emission requirements, but final testing showed it was impossible to do so even with the relatively mild requirements in 1968. That led to an expensive crash development program that produced the TR250, which was widely criticized at the time for offering almost no performance improvement over the TR4A. After the emergency passed, I'm sure that management was loathe to try again with the same PI system and ever-tougher US emission requirements, so the US only ever got the carbed version of TR6. Years later, during the final few years of TR7/TR8 production, some US-spec cars did get Bosch electronic fuel injection, but only because by then they couldn't meet California requirements with carbs.
There's no way a PI version can pass a smog inspection, because the inspection includes the "type approval" from the manufacturer. I mean, it's more than just a tailpipe sniffer test, you have to start with a smog certified car and then the test is only to confirm that it is operating to original specifications. However, I believe that 69 is old enough that you may not have to pass a smog inspection to bring it into the country. I don't know what Washington state law says, though.
State of tune will play a huge role in either case, and parts to adjust the mixture profile are very scarce for either setup. But in a very general sense, they should be roughly comparable. The PI tends to run rich (which kills fuel mileage) but also has higher compression which tends to improve it. From what I've heard though, the PI unit is nearly impossible to successfully rebuild yourself, while the carbs are much, much easier. For my money, unless you really want the sachet of having PI, it makes more sense to start with a US-spec TR6 and add the cam, compression & exhaust to get the same performance as PI. Kas Kastner used to claim that he could actually get more power with the ZS carbs than with the Lucas PI.